The site is accessible. 
Here's the last part of the debug log, maybe it can shadow a hint about what is not right.
GET /acme/authz/GXa0yULusIeOOmz9yVrXBos2NvUBmxyxf6vAW2P_ONg
Server response: array(3) {
  ["status"] => int(200)
  ["headers"] => array(10) {
    ["server"] => string(5) "nginx"
    ["content-type"] => string(16) "application/json"
    ["content-length"] => string(4) "1939"
    ["x-frame-options"] => string(4) "DENY"
    ["strict-transport-security"] => string(14) "max-age=604800"
    ["expires"] => string(29) "Wed, 22 Aug 2018 17:44:28 GMT"
    ["cache-control"] => string(29) "max-age=0, no-cache, no-store"
    ["pragma"] => string(8) "no-cache"
    ["date"] => string(29) "Wed, 22 Aug 2018 17:44:28 GMT"
    ["connection"] => string(5) "close"
  }
  ["body"] => string(1939) "{
  "identifier": {
    "type": "dns",
    "value": "mysite.pt"
  },
  "status": "invalid",
  "expires": "2018-08-29T17:44:14Z",
  "challenges": [
    {
      "type": "tls-sni-01",
      "status": "invalid",
      "url": "https://acme-v02.api.letsencrypt.org/acme/challenge/GXa0yULusIeOOmz9yVrXBos2NvUBmxyxf6vAW2P_ONg/6689620606",
      "token": "PADZOoAVTI0Lq_rt2tZf_pzvYcAa7n7-o9U9xUIskkY"
    },
    {
      "type": "http-01",
      "status": "invalid",
      "error": {
        "type": "urn:ietf:params:acme:error:unauthorized",
        "detail": "Invalid response from http://mysite.pt/.well-known/acme-challenge/a7j_h7YwVbSmb_Mbe16QHv4I1JWCFqtSLHjgsHn4wYs: \"\u003c!DOCTYPE html\u003e\n\u003chtml\u003e\n\u003chead\u003e\n\u003ctitle\u003e404 - Not Found\u003c/title\u003e\n\u003cmeta name=\"viewport\" content=\"width=device-width, initial-scale=1\"\"",
        "status": 403
      },
      "url": "https://acme-v02.api.letsencrypt.org/acme/challenge/GXa0yULusIeOOmz9yVrXBos2NvUBmxyxf6vAW2P_ONg/6689620607",
      "token": "a7j_h7YwVbSmb_Mbe16QHv4I1JWCFqtSLHjgsHn4wYs",
      "validationRecord": [
        {
          "url": "http://mysite.pt/.well-known/acme-challenge/a7j_h7YwVbSmb_Mbe16QHv4I1JWCFqtSLHjgsHn4wYs",
          "hostname": "mysite.pt",
          "port": "80",
          "addressesResolved": [
            "80.211.146.83"
          ],
          "addressUsed": "80.211.146.83"
        }
      ]
    },
    {
      "type": "dns-01",
      "status": "invalid",
      "url": "https://acme-v02.api.letsencrypt.org/acme/challenge/GXa0yULusIeOOmz9yVrXBos2NvUBmxyxf6vAW2P_ONg/6689620608",
      "token": "2_CQVQ3yzxE4sU1lrAld2R3i9bdzlBa8qB6jKLC8rvA"
    },
    {
      "type": "tls-alpn-01",
      "status": "invalid",
      "url": "https://acme-v02.api.letsencrypt.org/acme/challenge/GXa0yULusIeOOmz9yVrXBos2NvUBmxyxf6vAW2P_ONg/6689620609",
      "token": "fJ12bLA8Zf2gZTySHCqy7V8RLsC7AL0xWIqkOX1ayJA"
    }
  ]
}"
}